JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2006

  • question_answer
        The reason for the loss of optical activity of lactic acid when\[-OH\]group is changed by H is that

    A)  chiral centre of the molecule is destroyed

    B)  molecules acquires asymmetry

    C)  due to change in configuration

    D)  structural changes occurs

    Correct Answer: A

    Solution :

                    When\[-OH\]group of lactic acid is replaced by H then chiral carbon is lost. \[\underset{lactic\text{ }acid}{\mathop{C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\overset{\begin{smallmatrix}  H \\  | \end{smallmatrix}}{\mathop{C}}}\,-COOH}}\,\xrightarrow[{}]{{}}C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\overset{\begin{smallmatrix}  H \\  | \end{smallmatrix}}{\mathop{C}}}\,-COOH\] \[\therefore \]its optical activity is lost.


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