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JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2006

  • question_answer
        High basicity of IV^NH relative to\[M{{e}_{3}}N\]is attributed to

    A)  effect of solvent

    B)  inductive effect of Me

    C)  shape of \[M{{e}_{2}}NH\]

    D)  shape of\[M{{e}_{3}}N\]

    Correct Answer: A

    Solution :

                    Key Idea: Electrons donors are bases. Greater the stabilisation of cation formed by loss of electron more will be basicity of amine. \[2{}^\circ \]amine is more basic than 3° amine because \[2{}^\circ \]amine is stabilised by hydrogen bonding with solvent molecule.


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