JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2006

  • question_answer
        The rate constant of a first order reaction is\[6.9\times {{10}^{-3}}{{s}^{-1}}\]. How much time will it take to reduce the initial concentration to its 1/8th value?

    A)  100s                                     

    B)  200s

    C)  300s                                     

    D)  400s

    Correct Answer: C

    Solution :

                    Key Idea: Use the following formulae find correct answer. (i)            \[N={{N}_{0}}{{\left( \frac{1}{2} \right)}^{n}}\] (ii)           \[{{t}_{1/2}}=\frac{0.693}{k}\] (iii)          \[T=n\times {{t}_{1/2}}\] Given,       \[{{N}_{0}}=\]initial concentration = 1 N = concentration after time\[t=\frac{1}{8}\]                 \[k=6.9\times {{10}^{-3}}{{s}^{-1}}\]                 \[N={{N}_{0}}{{\left( \frac{1}{2} \right)}^{n}}\] Or           \[\frac{1}{8}=1{{\left( \frac{1}{2} \right)}^{n}}\] Or\[\therefore \]             \[n=3\]                 \[{{t}_{1/2}}=\frac{0.693}{k}=\frac{0.693}{6.9\times {{10}^{-3}}}=100s\]                 \[T=n\times {{t}_{1/2}}\]                 \[=3\times 100\] \[=300\text{ }s\] \[\therefore \] After 300 s it will be reduced to\[\frac{1}{8}\]of original concentration.


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