J & K CET Engineering J and K - CET Engineering Solved Paper-2015

  • question_answer
    For ion \[{{O}_{2}}^{-},\]the bond order is

    A)  2

    B)  1.5

    C)  2.5

    D)  0

    Correct Answer: B

    Solution :

     Number of electrons in\[O_{2}^{-}=8+8+1=17\] MO configuration of \[O_{2}^{-}=\sigma 1{{s}^{2}},{{\sigma }^{*}}1{{s}^{2}},\sigma 2{{s}^{2}},{{\sigma }^{*}}2{{s}^{2}},\] \[\sigma 2p_{z}^{2},\pi 2p_{x}^{2}\] \[\approx \pi 2p_{y}^{2},{{\pi }^{*}}2p_{x}^{2}\approx {{\pi }^{*}}2p_{y}^{1}\] Here, \[{{\text{N}}_{\text{b}}}\](bonding electrons) = 10           \[{{N}_{a}}\] (antibonding electrons) = 7 \[\because \] Bond order\[=\frac{{{N}_{b}}-{{N}_{a}}}{2}\] \[\therefore \] Bond order \[=\frac{10-7}{2}=15\]


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