J & K CET Engineering J and K - CET Engineering Solved Paper-2013

  • question_answer
    What will be the freezing point of 1% solution of glucose in water, given that molal depression constant for water is \[1.84\,\text{K}\,\text{mo}{{\text{l}}^{-}}\]

    A)  272.898 K         

    B) \[~0.102{{\,}^{o}}C\]

    C)  273 K             

    D) \[108{{\,}^{o}}C\]

    Correct Answer: A

    Solution :

     Mass of solution \[=100\text{ }g,\] Mass of glucose \[=1\text{ }g,\] Mass of solvent\[~=100-1=99\text{ }g\] \[\text{w}\,\text{=}\]mass of solute glucose,\[\text{W =}\]mass of solvent \[\text{m =}\]molar mass of solute \[\Delta {{T}_{f}}\times \frac{w}{m}\times \frac{1}{W/1000}\] \[=1.84\times \frac{1}{180}\times \frac{1}{99/1000}=0.103\] Freezing point of the solution \[=273-0.103\] \[=272.897\text{ }K\]


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