J & K CET Engineering J and K - CET Engineering Solved Paper-2009

  • question_answer
    The solubility product of a sparingly soluble metal hydroxide \[\text{M(OH}{{\text{)}}_{\text{2}}}\]at 298 K is\[\text{5}\times \text{1}{{\text{0}}^{-16}}\,mo{{l}^{3}}\,d{{m}^{-9}}.\]The pH value of its aqueous and saturated solution is

    A)  5               

    B)  9

    C)  11.5          

    D)  8.5

    Correct Answer: B

    Solution :

     \[M{{(OH)}_{2}}\rightleftharpoons \underset{s}{\mathop{{{M}^{+}}}}\,+\underset{2s}{\mathop{2O{{H}^{-}}}}\,\] \[{{K}_{sp}}=(s){{(2s)}^{2}}=4{{s}^{3}}=5\times {{10}^{-16}}\] \[\therefore \] \[s=\sqrt[3]{\frac{5\times {{10}^{-6}}}{4}}=5\times {{10}^{-6}}\] Cone. of \[O{{H}^{-}}=2\times 5\times {{10}^{-6}}={{10}^{-5}}\,\text{mol}\,\text{d}{{\text{m}}^{-3}}\] \[pOH=-\log [O{{H}^{-}}]\] \[=-\log {{10}^{-5}}=5\] \[pH=14-pOH=14-5=9.\]


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