J & K CET Engineering J and K - CET Engineering Solved Paper-2008

  • question_answer
    Dehydration of alcohol is an example of which type of reaction?

    A)  Substitution    

    B)  Elimination

    C)  Addition       

    D)  Rearrangement

    Correct Answer: B

    Solution :

     Dehydration of alcohol involves the loss of two atoms or groups from the adjacent carbon atoms, hence it is an example of (\[\beta -\]elimination reaction. \[\underset{\text{ethanol}}{\mathop{\overset{\beta }{\mathop{C}}\,{{H}_{3}}\overset{\alpha }{\mathop{C}}\,{{H}_{2}}OH}}\,\xrightarrow{+\,{{H}^{+}}}\overset{\beta }{\mathop{C}}\,{{H}_{3}}\overset{\alpha }{\mathop{C}}\,{{H}_{2}}\overset{+}{\mathop{O}}\,{{H}_{2}}\xrightarrow[-{{H}_{2}}O]{}\] \[\overset{\beta }{\mathop{C}}\,{{H}_{3}}\overset{\alpha }{\mathop{C}}\,H_{2}^{+}\xrightarrow[-{{H}^{+}}]{}\underset{\text{ethene}}{\mathop{\overset{\beta }{\mathop{C}}\,{{H}_{2}}}}\,=\overset{\alpha }{\mathop{C}}\,{{H}_{2}}\]


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