J & K CET Engineering J and K - CET Engineering Solved Paper-2008

  • question_answer
    When chlorine reacts with dil. \[\text{NaOH}\]under cold conditions, the oxidation state of chlorine changes from zero to

    A)  - 1 and + 5    

    B)  + 1 and + 4

    C)  + 5 and +3   

    D)  - 1 and + 1

    Correct Answer: D

    Solution :

     When chlorine reacts with dilute and cold \[\text{NaOH,}\]sodium chloride and sodium hypochloride are formed. \[2NaOH(cold)+C{{l}_{2}}\to NaCl+\underset{\begin{smallmatrix}  \,\,\,\,\,\,\,\,\,\text{soldium} \\  \text{hypochloride} \end{smallmatrix}}{\mathop{NaClO}}\,\,+{{H}_{2}}O\]Let oxidation state of Cl in NaCI is\[x.\] \[\text{NaCl}\] \[+\,1+x=0\] \[x=-1\] Let oxidation state of Cl in \[\text{NaClO}\]is \[x.\] \[\text{NaClO}\] \[\text{+}\,1+x-2=0\] \[x-1=0\] \[x=+1\] \[\therefore \]Oxidation states of chlorine changes from 0 to\[-1\] and \[+\,1.\]


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