J & K CET Engineering J and K - CET Engineering Solved Paper-2006

  • question_answer
    The reaction conditions used for converting 1, 2-dibromopropane to propylene are

    A)  \[KOH,alcohol/\Delta \]

    B) \[KOH,\text{ }water/\Delta \]

    C) \[~Zn,\text{ }alcohol/\Delta \]

    D) \[~Na,\text{ }alcohol/\Delta \]

    Correct Answer: C

    Solution :

     1, 2-dihalogen (vicinal) derivatives of the alkanes on reaction with zinc dust and methanol produces alkenes by loss of to halogen atoms (dehalogenation). \[\underset{1,2-\text{dibromopropane}}{\mathop{C{{H}_{3}}-\underset{Br}{\mathop{\underset{|}{\mathop{C}}\,}}\,H-\underset{Br}{\mathop{\underset{|}{\mathop{C}}\,}}\,{{H}_{2}}}}\,+Zn\xrightarrow{\text{alcohol/ }\!\!\Delta\!\!\text{ }}\] \[\underset{\text{propylene}}{\mathop{C{{H}_{3}}CH=C{{H}_{2}}}}\,\]


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