Haryana PMT Haryana PMT Solved Paper-2011

  • question_answer
    Catalyst \[SnC{{l}_{2}}\] / \[HCl\] is used in

    A)  Stephens reduction

    B)  Cannizaros reaction

    C)  Clemmensen reduction

    D)  Rosenmunds reduction

    Correct Answer: A

    Solution :

                    In the Stephens reduction, alkyl cyanide is reduced to aldehyde by  \[SnC{{l}_{2}}/HCl\]. \[RC\equiv N+2H\xrightarrow{SnC{{l}_{2}}/HCl}\underset{\begin{smallmatrix}  \text{aldimine} \\  \text{hydrochloride} \end{smallmatrix}}{\mathop{RCH=NH.HCl}}\,\]                                 \[\xrightarrow{{{H}_{2}}O}RCHO+N{{H}_{4}}Cl\]


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