Haryana PMT Haryana PMT Solved Paper-2009

  • question_answer
    Hydrolysis of \[PC{{l}_{5}}\] gives

    A) \[{{H}_{3}}P{{O}_{3}}\]        

    B)  \[HP{{O}_{3}}\]

    C)  \[{{H}_{3}}P{{O}_{2}}\]      

    D)  \[{{H}_{3}}P{{O}_{4}}\]

    Correct Answer: D

    Solution :

                    \[PC{{l}_{5}}\], on hydrolysis, with insufficient quantity of water, gives \[POC{{l}_{3}}\] while with excess of water gives phosphoric acid, \[({{H}_{3}}P{{O}_{4}})\]. \[PC{{l}_{5}}+4{{H}_{2}}O\xrightarrow{Excess\,of\,water}{{H}_{3}}P{{O}_{4}}+5HCl\]


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