Haryana PMT Haryana PMT Solved Paper-2006

  • question_answer
    \[{{C}_{6}}{{H}_{5}}-CH=CHCHO\xrightarrow{X}\]\[{{C}_{6}}{{H}_{5}}CH=CHC{{H}_{2}}OH\] In the above sequence X can be:

    A)  \[{{H}_{2}}/Ni\]

    B)  \[NaB{{H}_{4}}\]

    C)  \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}+{{H}^{+}}\]

    D)  both (a) and (b)

    Correct Answer: B

    Solution :

                    \[NaB{{H}_{4}}\] and \[LiAl{{H}_{4}}\] attacks only carbonyl group and reduce it into alcohol group. They do not attack on double bond. \[\underset{Cinnamic\,aldehyde}{\mathop{{{C}_{6}}{{H}_{5}}-CH=CHCHO\xrightarrow{NaB{{H}_{4}}}}}\,\] \[{{C}_{6}}{{H}_{5}}-\underset{Cinnamic\,acid}{\mathop{CH=CH.C{{H}_{2}}OH}}\,\]


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