CMC Medical CMC-Medical VELLORE Solved Paper-2013

  • question_answer
    Arrange these compounds in order of increasing\[{{S}_{N}}1\]reaction rate

    A)  \[IV<II<III<I\]

    B)  \[I<II<III<IV\]

    C)  \[IV<I<III<II\]

    D)  \[IV<I<II<III\]

    Correct Answer: A

    Solution :

                    \[S_{N}^{1}\] reaction is favoured for \[3{}^\circ \]alkyl halide. For a given system BE of \[C-Cl>C-Br,\]I with phenyl group gives resonance stabilized carbocation. Thus, increasing order is\[IV<II<III<\text{ }I\]


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