CMC Medical CMC-Medical Ludhiana Solved Paper-2015

  • question_answer
    Write the name of reagent to identify\[C{{o}^{2+}}.\]

    A)  \[N{{H}_{4}}CNS\]

    B)  Dimethyl glyoxime in \[N{{H}_{4}}OH\] / alcoholic solution or DMG

    C)  \[{{H}_{2}}S\]gas

    D)  None of the above

    Correct Answer: A

    Solution :

                    \[N{{H}_{4}}CNS\]is the reagent used to identify\[C{{o}^{2+}}.\] \[CoC{{l}_{2}}+4N{{H}_{4}}SCN\xrightarrow{{}}\]\[\underset{Blue\,\,colour}{\mathop{{{(N{{H}_{4}})}_{2}}[Co{{(SCN)}_{4}}]}}\,+2N{{H}_{4}}Cl\] \[N{{H}_{4}}CNS\]can be used to make distinction between \[C{{u}^{2+}}\]and \[C{{o}^{2+}}\]. \[CuC{{l}_{2}}+2N{{H}_{4}}SCN\xrightarrow{{}}\underset{Black\,ppt.}{\mathop{Cu{{(SCN)}_{2}}}}\,\downarrow +2N{{H}_{4}}Cl\]


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