A) optical isomers
B) coordinate isomers
C) ionisation isomers
D) linkage isomers
Correct Answer: C
Solution :
\[[Pt\,{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]B{{r}_{2}}\] complex on ionisation gives bromide ion, while \[[Pt\,{{(N{{H}_{3}})}_{4}}B{{r}_{2}}]C{{l}_{2}}\]on ionisation gives chloride ion. Hence, both complexes are related to each other as ionisation isomers. \[[Pt{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]B{{r}_{2}}\rightleftharpoons {{[Pt{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]}^{2+}}+2B{{r}^{-}}\] \[[Pt{{(N{{H}_{3}})}_{4}}B{{r}_{2}}]C{{l}_{2}}\rightleftharpoons {{[Pt{{(N{{H}_{3}})}_{4}}B{{r}_{2}}]}^{2+}}+2C{{l}^{-}}\]
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