Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2007

  • question_answer
    A solution of sodium metal in liquid ammonia is a strong reducing agent due to the presence of

    A)  sodium atoms    

    B)  sodium hydride

    C)  sodium amide    

    D)  solvated electron

    Correct Answer: D

    Solution :

    All alkali metals are soluble in liquid ammonia. \[Na+(x+y)N{{H}_{3}}\xrightarrow{{}}\underset{\begin{smallmatrix}  ammoniated \\  cation \end{smallmatrix}}{\mathop{N{{a}^{+}}{{(N{{H}_{3}})}_{x}}}}\,+\underset{\begin{smallmatrix}  ammoniated \\  electron \end{smallmatrix}}{\mathop{{{e}^{-}}{{(N{{H}_{3}})}_{y}}}}\,\] Due to presence of ammoniated electrons, sodium metal in liquid ammonia is a strong reducing agent.


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