Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2005

  • question_answer
    \[{{E}^{o}}=\frac{RT}{nF}\] In\[{{K}_{eq}},\] this equation is called    

    A)  Gibb's equation                       

    B)  Gibbs's-Helmholtz equation

    C)  Nernst equation

    D)  van der Waals' equation

    Correct Answer: C

    Solution :

    To determine the electrode potential (E) produced, Nemst gave the following equal: \[E={{E}^{o}}-\frac{RT}{nF}{{\log }_{n}}K\]           \[E={{E}^{o}}\] \[{{E}^{o}}=\frac{RT}{nF}{{\log }_{n}}K\]                 or            \[{{E}^{o}}=\frac{2.303RT}{nF}{{\log }_{10}}[{{M}^{n+}}]\] E = electrode potential developed \[{{E}^{o}}\]= standard reduction potential R = gas constant \[(8.3\text{ }J/K/mol)\] T = temperature, F = Faraday constant n = number of electron taking pans in reduction and oxidation


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