Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2005

  • question_answer
    In the equilibrium reaction, \[2HI(g)\rightleftharpoons {{H}_{2}}+{{I}_{2}}\] which of the following expressions is true?

    A)  \[{{K}_{p}}={{K}_{c}}\]

    B)  \[{{K}_{c}}=2{{K}_{p}}\]

    C)  \[{{K}_{p}}>{{K}_{c}}\]

    D)  \[{{K}_{c}}={{K}_{p}}{{(RT)}^{2}}\]

    Correct Answer: A

    Solution :

    \[2HI(g)\rightleftharpoons {{H}_{2}}(g)+{{I}_{2}}(g)\] \[\Delta n\] = (no of gaseous product) - (no of gaseous reactant)                 \[\Delta n=(2-2)=0\]                 \[{{K}_{p}}={{K}_{c}}{{(RT)}^{\Delta n}}\]             \[{{K}_{p}}={{K}_{c}}{{(RT)}^{0}}\]    When. \[\Delta n=0,\] then \[{{K}_{p}}={{K}_{c}}\] So,          \[{{K}_{p}}={{K}_{c}}\]


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