Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2004

  • question_answer
    In nitration of benzene with cone. \[HN{{O}_{3}}\] and cone. \[{{H}_{2}}S{{O}_{4}},\] the species which takes active part is

    A)  nitrite ion      

    B)  nitrate ion

    C)  nitroniumion  

    D)  nitrogen peroxide

    Correct Answer: C

    Solution :

    \[\underset{1-butene-3-yne}{\mathop{\underset{s{{p}^{2}}}{\mathop{\overset{1}{\mathop{C}}\,{{H}_{2}}}}\,=\underset{s{{p}^{2}}}{\mathop{\overset{2}{\mathop{C}}\,H}}\,-\underset{sp}{\mathop{\overset{3}{\mathop{C}}\,}}\,\equiv \underset{sp}{\mathop{\overset{4}{\mathop{C}}\,H}}\,}}\,\][ \[\because \] \[C-C\] \[\Rightarrow \]\[s{{p}^{3}},\]\[C=C\]\[\Rightarrow \]\[s{{p}^{2}},\] \[C\equiv C\]\[\Rightarrow \]\[sp\]] Thus, 1-butene-3yne contains only \[sp\]and \[s{{p}^{2}}\] hybridised carbons.


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