CET Karnataka Engineering CET - Karnataka Engineering Solved Paper-2010

  • question_answer
    During the adsorption of krypton on activated charcoal at low temperature

    A) \[\Delta H>0\] and \[\Delta S<0\]

    B) \[\Delta H<0\] and \[\Delta S<0\]

    C) \[\Delta H>0\] and \[\Delta S>0\]

    D) \[\Delta H<0\] and \[\Delta S>0\]

    Correct Answer: B

    Solution :

    Adsorption is an exothermic process, thus AH is negative (ie,\[\Delta H<0\]). Moreover, adsorption results in more ordered arrangements of molecules, thus entropy decreases (ie, \[\Delta S<0\]).                 \[\Delta G=\Delta H-T\Delta S\] Hence, low temperature favours the reaction.


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