CET Karnataka Engineering CET - Karnataka Engineering Solved Paper-2004

  • question_answer
    Benzoin is:

    A)  compound containing an aldehyde and a ketonic group

    B)  \[\alpha \], P-unsaturated acid

    C)  \[\alpha \]-hydroxy aldehyde

    D)  \[\alpha \]-hydroxy ketone

    Correct Answer: D

    Solution :

    Benzaldehyde when heated with ethanolic KCN, it gives \[\alpha \]-hydroxy ketone, benzoin. \[\underset{Benzaldehyde(2mol)}{\mathop{{{C}_{6}}{{H}_{5}}CHO+H-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-{{C}_{6}}{{H}_{5}}}}\,\xrightarrow[\Delta ]{alc\,\,KCN}\]                                 \[{{C}_{6}}{{H}_{5}}CH\underset{Benzoin}{\mathop{(OH)\,\,\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-{{C}_{6}}{{H}_{5}}}}\,\]


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