CET Karnataka Engineering CET - Karnataka Engineering Solved Paper-2003

  • question_answer
    Heat liberated with 100 ml of 1 N \[NaOH\] is neutralised by 300 ml of IN \[HCl\]:

    A)  11.56 kJ

    B)  5.73 kJ

    C)  22.92 kJ

    D)  17.19 kJ

    Correct Answer: B

    Solution :

    The molarity and normality are same in case of \[NaOH\] and \[HCl\] because the acidity and basicity of these are one and one respectively. Since, number of moles = molarity \[\times \]volume \[(l)\] \[\therefore \] No. of moles of \[NaOH\] solution                 \[=\frac{100\times 1}{1000}=0.1\] and number of moles of \[HCl\] solution                 \[=\frac{300\times 1}{1000}=0.3\] Hence, 0.1 mole \[NaOH\] is neutralised by mole \[HCl\]. We know that heat of neutralisation of 1 mole \[HCl\] and 1 mole \[NaOH\] is 57.3 kJ. Hence, heat of neutralisation of 0.1 mol \[HCl\] and 0.1 mole \[NaOH\] will be \[=57.3\times 0.1=5.73\,kJ\]


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