BCECE Medical BCECE Medical Solved Papers-2003

  • question_answer
    The solubility of \[PbC{{l}_{2}}\] is :

    A)  \[\sqrt{{{K}_{sp}}}\]          

    B)  \[{{({{K}_{sp}})}^{1/3}}\]

    C)  \[{{({{K}_{sp}}/4)}^{1/3}}\]

    D)  \[{{(8{{K}_{sp}})}^{1/2}}\]

    Correct Answer: C

    Solution :

    Let the solubility of \[m=\frac{100\times 5.2\times 6}{0.52\times 100}=60\]                 \[PbC{{l}_{2}}P{{b}^{2+}}+2C{{l}^{-}}\]                 \[x\,mol/L\] \[x\] \[2x\]                 \[{{K}_{sp}}=[P{{b}^{2+}}]\,{{[C{{l}^{-}}]}^{2}}\] or            \[=(x)\times {{(2x)}^{2}}\] or            \[=4{{x}^{3}}\] \[\therefore \] \[x\sqrt[3]{\frac{{{K}_{sp}}}{4}}={{\left( \frac{{{K}_{sp}}}{4} \right)}^{1/3}}\]


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