BCECE Engineering BCECE Engineering Solved Paper-2013

  • question_answer
    On adding \[\text{AgN}{{\text{O}}_{\text{3}}}\]solution into KI solution, a negatively charged colloidal sol. Is obtained when they are in

    A) \[100\,mL\,of0.1\text{ }M\,AgN{{O}_{3}}\text{ }+\text{ }100\,mL\,of0.1\text{ }M\,Kl\]

    B) \[100\,mL\,of0.1\text{ }M\,AgN{{O}_{3}}+100\,mL\,of0.2\text{ m}\,Kl\]

    C) \[100\,mL\,of0.2\text{ }M\,AgN{{O}_{3}}+100\,mL\,of0.1\text{ M}\,Kl\]

    D) \[100\,mL\,of0.15\text{ }M\,AgN{{O}_{3}}+100\,mL\,of0.15\text{ M}\,Kl\]

    Correct Answer: B

    Solution :

    Negatively charged colloidal sol is formed when \[\text{AgN}{{\text{O}}_{\text{3}}}\]is completely precipitated as Agl and extra Kl is absorbed on Agl \[A{{g}^{+}}+{{l}^{-}}\xrightarrow{{}}Agl\] \[Agl+{{l}^{-}}\xrightarrow{{}}{{[Agl]}^{-}}\] Thus,                     \[[A{{g}^{+}}]<[{{l}^{-}}]\]


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