BCECE Engineering BCECE Engineering Solved Paper-2013

  • question_answer
    Identify (A) and (B) in the following sequence of reactions. \[SnC{{l}_{2}}+2NaOH\xrightarrow{{}}(A)(white\,ppt)\]\[\xrightarrow[(excess)]{NaOH}(B)\]

    A) \[Sn{{(OH)}_{2}},N{{a}_{2}}Sn{{O}_{3}}\]

    B) \[Sn{{(OH)}_{2}},N{{a}_{2}}Sn{{O}_{2}}\]

    C) \[Sn{{(OH)}_{2}},N{{a}_{2}}[Sn{{(OH)}_{6}}]\]

    D) \[Sn{{(OH)}_{2}},\]no effect

    Correct Answer: B

    Solution :

    \[SnC{{l}_{2}}+2NaOH\xrightarrow{{}}\underset{\text{White}\,\text{ppt}}{\mathop{Sn{{(OH)}_{2}}}}\,\downarrow +2NaCl\] \[Sn{{(OH)}_{2}}+2NaOH\xrightarrow{{}}\underset{\text{sodium}\,\text{stannite}}{\mathop{N{{a}_{2}}Sn{{O}_{2}}}}\,+2{{H}_{2}}O\]


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