BCECE Engineering BCECE Engineering Solved Paper-2002

  • question_answer
    Which of the following compound is optically active?

    A) \[C{{H}_{3}}C{{H}_{2}}COOH\]  

    B) \[C{{H}_{3}}CHOHCOOH\]

    C) \[HOOC.C{{H}_{2}}.COOH\]

    D) \[C{{H}_{3}}.CO.COOH\]

    Correct Answer: B

    Solution :

    Key Idea: Optically active compound has at least one asymmetric or chiral carbon atom (a)\[C{{H}_{3}}-\underset{H}{\overset{H}{\mathop{\underset{|}{\overset{|}{\mathop{C}}}\,}}}\,-COOH\]         (b) \[C{{H}_{3}}-\underset{COOH}{\overset{H}{\mathop{^{*}\underset{|}{\overset{|}{\mathop{C}}}\,}}}\,-COOH\] (c) \[COOH-\underset{H}{\overset{H}{\mathop{\underset{|}{\overset{|}{\mathop{C}}}\,}}}\,-COOH\] \[C{{H}_{3}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-COOH\] Only choice (b) has asymmetric carbon atom (marked *) So it is optically active


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