NEET AIPMT SOLVED PAPER MAINS 2010

  • question_answer
    Which of the following expressions correctly represents the equivalent conductance at infinite dilution of \[A{{l}_{2}}{{(S{{O}_{4}})}_{3}}.\] Given that \[\Lambda {{_{Al}^{o}}^{3+}}\] and \[\Lambda _{SO_{4}^{2-}}^{o}\] are the equivalent conductance?s at infinite dilution of the respective ions?                                                               

    A) \[\text{2}{{\Lambda }^{\text{o}}}_{A{{l}^{3+}}}+3{{\Lambda }^{\text{o}}}_{so\frac{2-}{4}}\]      

    B)  \[{{\Lambda }^{\text{o}}}_{A{{l}^{3+}}}+{{\Lambda }^{\text{o}}}_{so\frac{2-}{4}}\]

    C)  \[\text{(}{{\Lambda }^{\text{o}}}_{A{{l}^{3+}}}+3{{\Lambda }^{\text{o}}}_{so\frac{2-}{4}})\times 6\]   

    D)  \[\frac{1}{3}{{\Lambda }^{\text{o}}}_{A{{l}^{3+}}}+\frac{1}{2}{{\Lambda }^{\text{o}}}_{so\frac{2-}{4}}\]

    Correct Answer: B

    Solution :

    \[A{{l}_{2}}{{(S{{O}_{4}})}_{3}}2A{{l}^{3+}}+3SO_{4}^{2-}\]. Since equivalent conductance?s are given only for ions, the equivalent conductance at infinite dilution, \[\Lambda _{eq}^{\infty }=\Lambda _{Al\,3+}^{o}+\Lambda _{so_{4}^{2-}}^{o}\]


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