JEE Main & Advanced AIEEE Solved Paper-2010

  • question_answer
      A solution containing 2.675 g of\[COC{{l}_{3}}\]⋅ \[6N{{H}_{3}}\](molar mass\[=267.5\text{ }g\,mo{{l}^{-1}}\]) is passed through a cation exchanger. The chloride ions obtained in solution were treated with excess of\[AgN{{O}_{3}}\]to give 4.78 g of\[AgCl\](molar mass\[=143.5\text{ }g\,mo{{l}^{-1}}\]). The formula of the complex is (At. mass of\[Ag=108\text{ }u\])       AIEEE  Solved  Paper-2010

    A) \[[COCl{{(N{{H}_{3}})}_{5}}]C{{l}_{2}}\]

    B) \[[CO{{(N{{H}_{3}})}_{6}}]C{{l}_{3}}\]

    C) \[[COCl{{(N{{H}_{3}})}_{4}}]Cl\]

    D) \[[COC{{l}_{3}}{{(N{{H}_{3}})}_{3}}]\]

    Correct Answer: B

    Solution :

    \[COC{{l}_{3}}\text{ }.6N{{H}_{3}}\xrightarrow[{}]{{}}AgCl\] \[4.75\,g\]or \[\frac{4.78}{143.5}=0.03\,m/s\]


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