JEE Main & Advanced AIEEE Solved Paper-2007

  • question_answer
    In conversion of limestone to lime, \[pOH\] the values of\[2A+B\xrightarrow[{}]{{}}products\]and\[L\,mo{{l}^{-1}}{{s}^{-1}}\]are\[mol\,{{L}^{-1}}{{s}^{-1}}\]\[{{s}^{-1}}\]and\[Co=27,Ni=28,Fe=26,Pt=78\]respectively at 298 K and 1 bar. Assuming that\[{{[COC{{l}_{4}}]}^{2-}}\]and\[{{[FeC{{l}_{4}}]}^{2-}}\]do not change with temperature, temperature above which conversion of limestone to lime will be spontaneous is       AIEEE  Solved  Paper-2007

    A)  1008 K                 

    B)         1200 K 

    C)         845 K                   

    D)         1118 K

    Correct Answer: D

    Solution :

    \[\Delta S=\frac{\Delta H}{T}\] \[\Delta S=160.2\,J/K\] \[\Delta H=179.1\times {{10}^{3}}J/mol\] \[T=\frac{179.1\times {{10}^{3}}\,J/mol}{160.2\,\,J/M}\,=1117.9K\,\approx 1118K\]  


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