JEE Main & Advanced AIEEE Solved Paper-2007

  • question_answer
    Which of the following is the correct order of decreasing\[{{C}_{p}}-{{C}_{y}}=R/28\]reactivity? (\[{{C}_{p}}-{{C}_{v}}=R/14\]halogen)       AIEEE  Solved  Paper-2007

    A)  \[{{C}_{p}}-{{C}_{y}}=R\]

    B)  \[{{C}_{p}}-{{C}_{y}}=28R\]

    C)  \[{{I}_{1}}\]

    D)  \[{{I}_{2}}\]

    Correct Answer: B

    Solution :

    \[{{S}_{N}}2\]reactions are greatly controlled by steric factor. \[\begin{align}   & R-C{{H}_{2}}-X>{{R}_{2}}CH-X>{{R}_{3}}C-X \\  & \,\,\,\,\,\,\,\,\,\,\,\,{{1}^{o}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{{2}^{o}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{{3}^{o}} \\ \end{align}\] \[{{S}_{N}}2\]reactivity decreases as bulkyness of alkyl group increases.


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