JEE Main & Advanced AIEEE Solved Paper-2007

  • question_answer
    In a saturated solution of the sparingly soluble strong electrolyte\[{{l}_{1}}\] (Molecular mass =283), the equilibrium which sets in, is \[{{l}_{2}}\] If the solubility product constant, \[{{k}_{1}}\]of\[{{k}_{2}},\]at a given temperature is\[({{K}_{2}}{{l}_{2}}{{T}_{1}}+{{K}_{1}}{{l}_{1}}{{T}_{2}})/({{K}_{1}}{{l}_{1}}+{{K}_{2}}{{l}_{2}})\] what is the mass of \[({{K}_{2}}{{l}_{1}}{{T}_{1}}+{{K}_{1}}{{l}_{2}}{{T}_{2}})/({{K}_{2}}{{l}_{1}}+{{K}_{1}}{{l}_{2}})\]contained in 100 mL of its saturated solution?       AIEEE  Solved  Paper-2007

    A)  \[({{K}_{1}}{{l}_{2}}{{T}_{1}}+{{K}_{2}}{{l}_{1}}{{T}_{2}})/({{K}_{1}}{{l}_{2}}+{{K}_{2}}{{l}_{1}})\]

    B)         \[({{K}_{1}}{{l}_{1}}{{T}_{1}}+{{K}_{2}}{{l}_{2}}{{T}_{2}})/({{K}_{1}}{{l}_{1}}+{{K}_{2}}{{l}_{2}})\]

    C)  \[{{C}_{p}}\]     

    D)         \[{{C}_{y}}\]

    Correct Answer: B

    Solution :

    \[\frac{1}{\sqrt{2}}\]depends on the solubility or vice versa. Solubility is the maximum mass of solutes (in grams) dissolved in one litre of solubility. Therefore, find the solubility from\[\frac{\sqrt{3}}{2}\]and then, calculate mass. \[Agl{{O}_{3}}\,(s)\,A{{g}^{+}}\,(aq)\,+lO_{3}^{-}(aq)\] Let solubility of\[\frac{3}{4}\]be S \[{{K}_{sp}}\,=[A{{g}^{+}}]\,[lO_{3}^{-}]\] \[{{k}_{2}},\] or        \[I\] In 1000 mL mol of\[{{I}_{0}}\]dissolved\[{{k}_{1}}\] mol In 100 mL of mole of\[{{k}_{2}}\]dissolved\[f/2\] mol Mass of\[f/4\]in \[4f\]                                                 \[2f\]


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