JEE Main & Advanced AIEEE Solved Paper-2006

  • question_answer
    Which of the following chemical reactions depicts the oxidizing behavior of\[{{H}_{2}}S{{O}_{4}}\]?     AIEEE  Solved  Paper-2006

    A) \[2HI+{{H}_{2}}S{{O}_{4}}\to {{I}_{2}}+S{{O}_{2}}+{{H}_{2}}O\]

    B) \[Ca{{(OH)}_{2}}+{{H}_{2}}S{{O}_{4}}\to CaS{{O}_{4}}+2{{H}_{2}}O\]

    C) \[NaCl+{{H}_{2}}S{{O}_{4}}\to NaHS{{O}_{4}}+HCl\]

    D) \[2PC{{l}_{5}}+{{H}_{2}}S{{O}_{4}}\to 2POC{{l}_{3}}+2HCl+S{{O}_{2}}C{{l}_{2}}\]

    Correct Answer: A

    Solution :

    \[\overset{-1}{\mathop{2Hl}}\,+\overset{+6}{\mathop{{{H}_{2}}S{{O}_{4}}}}\,\xrightarrow{{}}\overset{0}{\mathop{{{l}_{2}}}}\,+\overset{4}{\mathop{S{{O}_{2}}}}\,+2{{H}_{2}}O\] \[\underset{\begin{smallmatrix}  Oxidi\sin g \\  agent \end{smallmatrix}}{\mathop{{{H}_{2}}S{{O}_{4}}}}\,-\operatorname{Re}duced\,to\xrightarrow{\,}S{{O}_{2}}\]


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