JEE Main & Advanced AIEEE Solved Paper-2005

  • question_answer
    The reaction, \[R-\overset{\begin{smallmatrix}  O \\  |\,| \end{smallmatrix}}{\mathop{C}}\,-X+N{{u}^{\text{O-}}}\]                                 \[\xrightarrow{{}}R-\overset{\begin{smallmatrix}  O \\  |\,| \end{smallmatrix}}{\mathop{C}}\,-Nu+{{X}^{\text{O-}}}\] is fastest when X is     AIEEE  Solved  Paper-2005

    A) \[OCOR\]          

    B)        \[O{{C}_{2}}{{H}_{5}}\] 

    C)        \[N{{H}_{2}}\]                  

    D)        \[Cl\]

    Correct Answer: D

    Solution :

    \[R-\overset{\begin{smallmatrix}  O \\  |\,| \end{smallmatrix}}{\mathop{C}}\,-x+N{{u}^{-}}\xrightarrow{{}}R-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-Nu+{{X}^{-}}\] Best leaving group (poorest nucleophile) is \[C{{l}^{-}}\]thus fastest reaction is with\[Cl\].


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