JEE Main & Advanced AIEEE Solved Paper-2005

  • question_answer
    In which of the following arrangements the order is not according to the property indicated against it?     AIEEE  Solved  Paper-2005

    A) \[Li<Na<K<Rb\]: Increasing metallic radius

    B) \[I<Br<F<Cl\]: Increasing electron gain enthalpy (with negative sign)

    C) \[B<C<N<O\]: Increasing first ionization enthalpy

    D) \[A{{l}^{3+}}<M{{g}^{2+}}<N{{a}^{+}}<{{F}^{-}}\]: Increasing ionic size

    Correct Answer: C

    Solution :

    Metallic radii increase in a group from top to bottom. Thus,\[Li<Na<K<Rb\]is True Electron gain of enthalpy of\[Cl>F\]and decreases along a group. Thus, \[l<Br<F<Cl\] is true. Ionisation enthalpy increases along a period left to right but due to presence of half-filled orbitals in N, ionisation enthalpy of\[N>0\]. Thus,\[B<C<N<O\]is incorrect. Larger the (-) ve charge, larger the size and larger the (+) ve charge, simaller the size for isoelectronic species Thus,\[A{{l}^{3+}}<M{{g}^{2+}}<\] \[N{{a}^{+}}<{{F}^{-}}\]is true.


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