JEE Main & Advanced AIEEE Solved Paper-2002

  • question_answer
    The metallic sodium dissolves in liquid ammonia to form a deep blue coloured solution. The deep blue colour is due to formation of   AIEEE  Solved  Paper-2002

    A) solvated electron, \[{{e}^{-}}(N{{H}_{3}})_{x}^{-}\]

    B) solvated atomic sodium, \[Na{{(N{{H}_{3}})}_{y}}\]

    C) \[(N{{a}^{+}}+N{{a}^{-}})\]            

    D)           \[NaN{{H}_{2}}+{{H}_{2}}\]

    Correct Answer: A

    Solution :

    All alkali metals dissolve in liquid ammonia \[M+(x+y)N{{H}_{3}}\xrightarrow{{}}{{M}^{+}}{{(N{{H}_{3}})}_{x}}+{{e}^{-}}{{(N{{H}_{3}})}_{y}}\] These electrons are excited to higher energy levels and the absorption of photons occurs in the red region of the spectrum. Thus, solution appears blue.


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