JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Sample Paper Topic Test - Thermo Chemistry (Thermodynamics)

  • question_answer
    In an adiabatic process non-transfer of heat takes place between system and surroundings. Choose the correct option for free expansion of an ideal gas under adiabatic condition from the following.

    A) \[q=0,\Delta T,w=0\]

    B) \[q\ne 0,\Delta T=0,w=0\]

    C) \[q=0,\Delta T=0,w=0\]

    D) \[q=0,\Delta t<0,w\ne 0\]

    Correct Answer: A

    Solution :

    [a] Free expansion \[w=0\]
    adiabatic process \[q=0\]
    \[\Delta U=q+w=0,\] this means internal energy remains constant.  
    \[\therefore \]      \[\Delta t=0\]
    In ideal gas there is no intermolecular attraction. Hence such a gas expands under adiabatic conditions into a vaccum no heat is absorbed or evolved since no external work is done to seperate the molecules.


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