12th Class Chemistry Sample Paper Chemistry Sample Test Paper-6

  • question_answer
      (i) Extraction of Au by leaching with NaCN involves both oxidation and reduction. Justify by giving equations for the reactions involved. (ii) Why is froth floatation method selected for the concentration of sulphide ores?                        [2]

    Answer:

      (i) Extraction of Au (gold) by leaching with NaCN involves. (a) Oxidation of gold (Au) to by (g) complexes with cyanide forming .  (b) When complex is treated with active metal (as Zn), pure metal is displaced. This involves reduction.      [1] Thus, method involves redox reaction. (ii) Powdered ore is suspended in water in a large vat, together with suitable additives, (pine oil as frother and ethyl xanthate as collector) and the mixture is agitated with air. Particles of ore become attached to the air bubbles rise to the top of the vat and are collected in the over flow froth. Particles of the undesired waste rock (gangue) fall to the bottom. Thus, this is based on the difference in wet ability of different minerals.               [1]


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