12th Class Chemistry Sample Paper Chemistry Sample Test Paper-2

  • question_answer
      State reasons for the following. (i) the d4 species, is strongly reducing while manganese (III) is strongly oxidising. (ii) The d configuration is very unstable in ions. (iii) Cobalt (II) is sable in aqueous solution but in the presence of complexing reagents it is easily oxidised.                                            []

    Answer:

      (i)           When  is oxidised there is no effect on the stability. Thus  is a reducing agent. When is reduced to  stability increases. Thus is an oxidising agent.       [1] (ii) We can consider the case of Sc (21)   is unstable and is easily oxidised to  to attain stable configuration of the inert gas  Thus, 3d1 configuration is very unstable in ion. [1] (iii) Thus is oxidised to when complexing takes place.


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