A) \[C{{H}_{3}}\overset{\bullet }{\mathop{C}}\,HC{{H}_{2}}Cl\]
B) \[C{{H}_{3}}\overset{\oplus }{\mathop{C}}\,HC{{H}_{3}}\]
C) \[C{{H}_{3}}C{{H}_{2}}\overset{\bullet }{\mathop{C}}\,{{H}_{2}}\]
D) \[C{{H}_{3}}C{{H}_{2}}\overset{\oplus }{\mathop{C}}\,{{H}_{2}}\]
Correct Answer: B
Solution :
The reaction proceed through Markownikoff's rule by ionic mechanism. The initial carbonium ion \[(C{{H}_{3}}C{{H}_{2}}\overset{+}{\mathop{C}}\,{{H}_{2}})\] rearrange into more stable \[(C{{H}_{3}}\overset{+}{\mathop{C}}\,HC{{H}_{3}})\] carbonium ion.
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