JEE Main & Advanced Sample Paper JEE Main Sample Paper-39

  • question_answer
    Which of the following compounds are not arranged in order of decreasing reactivity towards electrophilic substitution?

    A)  Methoxy benzene > Toluene > Bromo benzene

    B)  Phenol > N-Propyl benzene > Benzoic acid

    C)  Chlorotoluene > Para Nitro toluene > 2-chloro-4-Nitrotoluene

    D)  Benzoic acid > Phenol > N-Propyl benzene

    Correct Answer: D

    Solution :

     Amongst the sets, it is [d] that is not arranged in the order of decreasing reactivity towards electrophilic substitution. Carboxylic acid group in the case of benzoic acid deactivates the benzene nucleus towards electrophilic substitution reaction and thus it cannot have higher reactivity than phenol which has a highly activating phenolic OH group.


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