JEE Main & Advanced Sample Paper JEE Main Sample Paper-31

  • question_answer
    If the cell reaction are given as
    (i) \[F{{e}^{2+}}(g)+2{{e}^{-}}\xrightarrow{{}}Fe(s)\,;\,{{E}^{o}}=-0.44\,V\]
    (ii) \[2{{H}^{+}}(aq)+\frac{1}{2}{{O}_{2}}(g)+2{{e}^{-}}\to {{H}_{2}}O(\ell )\,;\,{{E}^{o}}=+1.23\,V\]the \[{{E}^{o}}\] for the reaction,
    \[Fe(s)+2{{H}^{+}}+\frac{1}{2}{{O}_{2}}(g)\xrightarrow{{}}F{{e}^{2+}}(aq)+{{H}_{2}}O(\ell )\] is :

    A) \[+1.67\,V\]   

    B)                                    \[-1.67\,V\]

    C) \[+0.79\,V\]         

    D) \[-0.79\,V\]

    Correct Answer: A

    Solution :

    \[E_{cell}^{^{o}}=E_{OP}^{o}+E_{RP}^{o}=0.44+1.23=1.67V\]


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