JEE Main & Advanced Sample Paper JEE Main Sample Paper-17

  • question_answer
    Ethanol cannot be dried by anhydrous \[\text{CaC}{{\text{l}}_{\text{2}}}\] due to the formation of which of the following solvated products?

    A) \[CaC{{l}_{2}}.2{{C}_{2}}{{H}_{5}}OH\]

    B) \[2CaC{{l}_{2}}.3{{C}_{2}}{{H}_{5}}OH\]

    C)  \[CaC{{l}_{2}}.4{{C}_{2}}{{H}_{5}}OH\]

    D)  \[CaC{{l}_{2}}.{{C}_{2}}{{H}_{5}}OH\]

    Correct Answer: C

    Solution :

     Ethanol forms a solid derivative with metallic salt in which alcohol molecule shows solvation phenomena, e.g., \[\text{CaC}{{\text{l}}_{\text{2}}}\text{.4}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\text{OH}\text{.}\]That is why alcohols cannot be dried by anhydrous \[\text{CaC}{{\text{l}}_{2}}.\]


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