JEE Main & Advanced Sample Paper JEE Main Sample Paper-12

  • question_answer
    For the reaction\[A(g)+2B(g)C(g)+\]\[D(g);\]\[{{K}_{C}}={{10}^{12}}\]. If the initial moles of A, B, C and D are 0.5, 1, 0.5 and 3.5 moles respectively in a one litre vessel. What is the equilibrium concentration of B?

    A)  \[{{10}^{-4}}\]                                 

    B)  \[2\times {{10}^{-4}}\]

    C)  \[4\times {{10}^{-4}}\]                 

    D)  \[8\times {{10}^{-4}}\]

    Correct Answer: B

    Solution :

     \[A(g)+2B(g)C(g)+D(g)\] At \[\underset{\approx y}{\mathop{e{{q}^{n}}0.5-x}}\,\underset{\approx 2y}{\mathop{1-x}}\,\underset{\approx 1}{\mathop{0.5+x}}\,\underset{\approx 4}{\mathop{3.5+x}}\,\] (due to very high value of equilibrium constant) \[{{10}^{12}}=\frac{1\times 4}{y\times {{(2y)}^{2}}};y={{10}^{-4}}\] \[[B(g)]=2y\to 2\times {{10}^{-4}}\]


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