JEE Main & Advanced Sample Paper JEE Main - Mock Test - 7

  • question_answer
    Calculate the enthalpy of formation of \[NC{{l}_{3}}(g)\] in terms of x, y and z.
    Given:
    I. \[N{{H}_{3(g)}}+3C{{l}_{2(g)}}\to NC{{l}_{3(g)}}+3HC{{l}_{(g),}}\Delta {{H}_{1}}=x\]
    II. \[{{N}_{2(g)}}+3{{H}_{2(g)}}\to 2N{{H}_{3(g)}},\Delta {{H}_{2}}=y\]
    III. \[{{H}_{2(g)}}+C{{l}_{2(g)}}\to 2HC{{l}_{(g)}},\Delta {{H}_{3}}=z\]

    A)  \[x-\frac{y}{2}+\frac{3z}{2}\]                    

    B)  \[x+\frac{y}{2}-\frac{3z}{2}\]

    C)  \[x+(y-3z)\]                

    D)  \[x-y+3z\]

    Correct Answer: B

    Solution :

     \[\frac{1}{2}{{N}_{2}}+\frac{3}{2}C{{l}_{2}}\to NC{{l}_{3}}\]
    [b] \[\Delta H=?\] \[\Delta H=\Delta {{H}_{1}}+\frac{1}{2}\Delta {{H}_{2}}-\frac{2}{3}\Delta {{H}_{3}}\] \[=x+\frac{1}{2}y-\frac{2}{3}z\] \[=x+\frac{1}{2}(y-3z)\]


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