JEE Main & Advanced Sample Paper JEE Main - Mock Test - 22

  • question_answer
    In the 'ring test' for \[N{{O}_{3}}^{\Theta }\] ion, a complex (X) is formed. The oxidation state of \[Fe,\]charge on \[(NO)\] species and magnetic moment of the complex species (X) are, respectively,

    A) \[+1,+1,\sqrt{15\,}BM.\] 

    B) \[+2,+1,\sqrt{15\,}\,BM.\]

    C) \[+2,+1,\sqrt{35\,}\,BM.\]

    D) \[+1,0,\sqrt{35\,}\,BM.\]

    Correct Answer: A

    Solution :

    [a] Complex (X) is:  \[{{\left[ \overset{+1}{\mathop{Fe}}\,{{({{H}_{2}}O)}_{5}}N{{O}^{\oplus }} \right]}^{2+}}.S{{O}_{4}}^{2-}\] It has 3 unpaired \[\bar{e}'s\]. So   \[{{\mu }_{MM}}=\sqrt{n(n+2)}=\sqrt{3(3+3)}=\sqrt{15}BM\]


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