JEE Main & Advanced Chemistry Analytical Chemistry Question Bank Wet Test for Basic Radical

  • question_answer
    Ferric ion forms a prussian blue coloured ppt. due to [CPMT 1980; BHU 1980; MP PET 1995; Kurukshetra CEE 1998; RPET 1999; MP PMT 2001]

    A) \[{{K}_{4}}Fe{{(CN)}_{6}}\]

    B) \[F{{e}_{4}}{{\left[ Fe{{(CN)}_{6}} \right]}_{3}}\]

    C) \[KMn{{O}_{4}}\]

    D) \[Fe{{(OH)}_{3}}\]

    Correct Answer: B

    Solution :

    \[4FeC{{l}_{3}}+3{{K}_{4}}\left[ Fe{{(CN)}_{6}} \right]\]\[\to \underset{\begin{smallmatrix}  \text{Prussian}\,\, \\  \text{Blue colour} \end{smallmatrix}}{\mathop{F{{e}_{4}}{{\left[ Fe{{(CN)}_{6}} \right]}_{3}}}}\,+12KCl\]


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