JEE Main & Advanced Chemistry Some Basic Concepts of Chemistry / रसायन की कुछ मूलभूत अवधारणाएँ Question Bank Topic Test - Some Basic Concepts of Chemistry

  • question_answer
    1 mol of a gaseous aliphahatic compound\[{{C}_{n}}{{H}_{3n}}{{O}_{m}}\] is completely burnt in an excess of oxygen. The contraction in volume is (assume water get condensed out)

    A) \[\left( 1+\frac{1}{2}n-\frac{3}{4}m \right)\]

    B) \[\left( 1+\frac{3}{4}n-\frac{1}{4}m \right)\]

    C) \[\left( 1-\frac{1}{2}n-\frac{3}{4}m \right)\]

    D)             \[\left( 1+\frac{3}{4}n-\frac{1}{2}m \right)\]

    Correct Answer: D

    Solution :

    [d] \[{{C}_{n}}{{H}_{3n}}{{O}_{m}}+y{{O}_{2}}\xrightarrow[{}]{{}}nC{{o}_{2}}(g)+\frac{3n}{2}{{H}_{2}}O(l)\]
    Contraction in volume= Contraction in moles of gas \[=1\frac{3n}{4}-\frac{m}{2}\]
    \[=1+\frac{3n}{4}-\frac{m}{2}\]
    \[\Rightarrow \]   \[\left( 2n+\frac{3n}{2}-m \right)\times \frac{1}{2}=y\]
    \[\Rightarrow \]   \[n+\frac{3n}{4}-\frac{m}{2}=y\]


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