JEE Main & Advanced Chemistry Alcohols, Phenols and Ethers / एल्कोहॉल, फीनॉल तथा ईथर Question Bank Properties of alcohol Phenol and Ethers

  • question_answer
    If there be a compound of the formula \[C{{H}_{3}}C{{(OH)}_{3}}\] which one of the following compounds would be obtained from it without reaction with any reagent         [CPMT 1983]

    A)                 \[C{{H}_{3}}OH\]             

    B)                 \[{{C}_{2}}{{H}_{5}}OH\]

    C)                 \[C{{H}_{3}}COOH\]       

    D)                 HCHO

    Correct Answer: C

    Solution :

               \[C{{H}_{3}}-C\,<-\begin{matrix}    OH  \\    OH  \\    OH  \\ \end{matrix}\to C{{H}_{3}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-OH+{{H}_{2}}O\]            If two or more \[-OH\] groups are present on carbon atom then it immediately looses water molecule and forms acid or aldehyde.            Two\[-OH\]groups on the same carbon aldehyde is formed            \[\underset{\text{Unstable}}{\mathop{R-CH<\begin{matrix}    OH  \\    OH  \\ \end{matrix}}}\,\xrightarrow[-{{H}_{2}}O]{}\underset{\text{Aldehyde}}{\mathop{R-\underset{\underset{H}{\mathop{|}}\,}{\mathop{C}}\,=O}}\,\]            Three \[-OH\] groups on the same carbon acid is formed.                                 \[R-C<-\begin{matrix}    OH  \\    OH  \\    OH  \\ \end{matrix}\xrightarrow[-{{H}_{2}}O]{}R-C<\underset{\text{acid}}{\mathop{\,\,\,\,\,\begin{matrix}    OH  \\    O\,\,\,  \\ \end{matrix}}}\,\]


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