JEE Main & Advanced Chemistry Alcohols, Phenols and Ethers / एल्कोहॉल, फीनॉल तथा ईथर Question Bank Properties of alcohol Phenol and Ethers

  • question_answer
    Ethylene glycol reacts with excess of \[PC{{l}_{5}}\] to give [Kerala PMT 2004]

    A)                 1, 1-dichloroethane

    B)                 1, 2-dicholoroethane

    C)                 1, 1, 1-trichloroethane

    D)                 1, 1, 2, 2-tetrachloroethane

    E)                 2, 2-dichloroethane

    Correct Answer: B

    Solution :

                    \[\underset{\text{Ethylene glycol}}{\mathop{\underset{C{{H}_{2}}OH}{\mathop{\underset{|}{\mathop{C}}\,{{H}_{2}}OH}}\,}}\,+2PC{{l}_{5}}\to \underset{\text{1, 2 dichloroethane}}{\mathop{\underset{C{{H}_{2}}Cl}{\mathop{\underset{|}{\mathop{C}}\,{{H}_{2}}Cl}}\,+2POC{{l}_{3}}+2HCl}}\,\]


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