A) Formic acid
B) Oxalic acid
C) Allyl alcohol
D) Glycerol trioxalate
Correct Answer: A
Solution :
\[\underset{C{{H}_{2}}-OH}{\overset{C{{H}_{2}}-OH}{\mathop{\underset{|\,\,\,\,}{\overset{|\,\,\,\,}{\mathop{CH}}}\,-OH\,\,\,}}}\,+\begin{matrix} COOH \\ \overset{|}{\mathop{C}}\,OOH \\ \end{matrix}\underset{-{{H}_{2}}O}{\mathop{\xrightarrow{{{110}^{o}}C}}}\,\underset{\text{Glycerol}\,\,\text{mono-oxolate}}{\mathop{\underset{C{{H}_{2}}-OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}{\overset{C{{H}_{2}}-O-CO-COOH}{\mathop{\underset{|\,\,\,\,}{\overset{|\,\,\,\,}{\mathop{CH}}}\,-OH\,\,\,\,\,\,\,\,\,\,\,\,\,\xrightarrow[-C{{O}_{2}}]{}}}}\,}}\,\]\[\underset{\text{Glycerol}\,\,\text{mono-formate}}{\mathop{\underset{C{{H}_{2}}-OH\,\,\,\,\,\,\,\,\,\,\,\,\,}{\overset{C{{H}_{2}}-O-CO-H}{\mathop{\underset{|\,\,\,\,}{\overset{|\,\,\,\,}{\mathop{CH}}}\,-OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}}}\,}}\,\xrightarrow{\text{Hydrolysis}}\underset{\text{Formic}\,\,\text{acid}}{\mathop{\underset{HCOOH}{\mathop{\underset{+}{\mathop{\underset{C{{H}_{2}}-OH}{\overset{C{{H}_{2}}-OH}{\mathop{\underset{|\,\,\,\,}{\overset{|\,\,\,\,}{\mathop{CH}}}\,-OH\,\,\,\,}}}\,}}\,}}\,}}\,\]
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